A new environmental friendly method for the preparation of sugar acids via catalytic oxidation on gold catalysts

A novel and efficient way of producing of aldonic acids is reported. The selective catalytic oxidation of monosaccharides (arabinose, ribose, xylose, lyxose, mannose, rhamnose, glucose, galactose, N-acetyl-glucosamine) and disaccharides (lactose, maltose, cellobiose, melibiose) on Au, Pd and Pt catalysts was investigated. By using the gold catalyst, a total selectivity with respect to aldonic acids and a high catalytic activity for all investigated sugars was found. The reaction conditions for the production of maltobionic and lactobionic acids via oxidation on gold catalysts were optimised. A high long-term stability of two different gold catalysts for the oxidation of maltose and lactose, respectively, was found. (c) 2006 Elsevier B.V. All rights reserved.