4.5 Article

Transient amino-hydrazino-carbenes:: A radical pathway for intramolecular 1,2-migration reactions

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2007, Issue 6, Pages 912-917

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600901

Keywords

carbenes; 1,2-migration; radical process; DFT calculations

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The transient amino-hydrazino-carbenes 2c-e are reported to undergo intramolecular 1,2-migration reactions that proceed through a radical pathway according to DFT calculations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

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