Journal
ORGANIC LETTERS
Volume 9, Issue 3, Pages 385-388Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062468y
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- NCI NIH HHS [CA-109164] Funding Source: Medline
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An enantioselective synthesis of the chiral bisnaphthopyrone natural product nigerone is reported. The key step was an eight-step isomerization process to form the final natural product. The isomerization precursor was constructed via asymmetric oxidative biaryl coupling of an advanced intermediate with a 1,5-diaza-cis-decalin copper catalyst.
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