Journal
ORGANIC LETTERS
Volume 9, Issue 3, Pages 421-424Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062705x
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The first synthesis of the pyrrolidinone core of the polyene beta-lactone antibiotic KSM-2690 B is described. An ammonia-free Birch reductive aldol reaction utilizing acetaldehyde is one of the key steps, together with a ruthenium-catalyzed alkene isomerization reaction.
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