Journal
MACROMOLECULAR RESEARCH
Volume 15, Issue 1, Pages 17-21Publisher
POLYMER SOC KOREA
DOI: 10.1007/BF03218747
Keywords
poly(amide-sulfone)s; vinyl sulfone; Michael addition; tertiary amine
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A series of new, vinyl sulfone-containing monomers was prepared by p-aminophenyl vinyl sulfone (1) with various acid chlorides such as adipoly chloride, terephthaloyl chloride and isophthaloyl chloride. Finally, tertiary amine-containing poly(amide-sulfone)s were prepared by the Michael-type addition polymerization using N,N-dimethylethylenediamine (DMEDA), p-phenylenediamine and piperazin. To evaluate the relevant properties for permselective membranes and enzyme substrate, various physical properties such as molecular weight, solubility, quaternization behavior and thermal properties were examined.
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