Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 262, Issue 1-2, Pages 67-76Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2006.08.067
Keywords
heteropoly acid; polyoxometalate; Keggin-type structure; Wells-Dawson type structure; epoxidation of alkene; alcohol oxidation; phenol hydroxylation; prins cyclization; cycloaddition
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Polyoxometalates (abbreviated as POMs) are useful acids and oxidation catalysts in various reactions since its catalytic features can be controlled at a molecular level. This review summarizes some recent research progress in catalytic application of Keggin and Wells-Dawson type polyoxometalates. Particular attention is given to most developments of our recent studies on the use of POMs as heterogeneous and homogeneous catalysts for the selective oxidation and acid-catalyzed reactions. (c) 2006 Elsevier B.V. All rights reserved.
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