Journal
ORGANIC LETTERS
Volume 9, Issue 3, Pages 405-408Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062723e
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Chemoselective dehydrogenative interaction of ClMe2SiH with a carboxylic acid group in the presence of InX3 is reported. C-13 NMR investigation revealed the formation of PhCOOSi(Cl)Me-2 as the major transient intermediate. Chemo- and regioselective Friedel-Crafts acylation of aromatic ethers directly from carboxylic acids was established.
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