Journal
ELECTROCHIMICA ACTA
Volume 52, Issue 7, Pages 2595-2602Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2006.09.015
Keywords
electrochemical cell characterization; diamond electrodes; water disinfection; OER mechanism; reactive oxygen species
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Laboratory experiments were performed to characterize the behaviour of an electrochemical cell equipped with boron-doped diamond anodes and to verify its effectiveness in water disinfection. The hydrodynamic regime was determined when the cell worked either in batch or in continuous mode. Galvanostatic electrolyses of aqueous 1 mM NaSO4 solutions were performed to investigate on the oxidant production in different experimental conditions. The same solutions contaminated by E. coli, enterococci and coliforms were used as test media to verify the effectiveness of the system in the disinfection process. Experimental results indicated that the major inactivation mechanism of bacteria in the electrochemical cell is a disinfection by electrochemically generated oxidants, however a cooperative effect of superficial reaction has to be taken into account. The great capability of BDD anode to produce reactive oxygen species (ROS) and other oxidizing species during the electrolysis allows to establish a chlorine-free disinfection process. (c) 2006 Elsevier Ltd. All rights reserved.
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