Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 49, Pages 16215-16218Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809934
Keywords
cross-olefination; diazo compounds; homogenous catalysis; ruthenium; sulfur ylides
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Funding
- DFG [MA 4861/4-2]
- ERC (CoG VINCAT)
- Covestro AG
- University of Vienna
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A ruthenium-catalysed cross-olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.
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