Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 39, Pages 12865-12868Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805915
Keywords
boranes; hydride ligands; molybdenum; N-2 reduction; nitride functionalization
Categories
Funding
- CNRS
- Universite de Toulouse
- Region Midi-Pyrenees
- IDEX of the Universite Federale Toulouse Midi-Pyrenees
- ANR
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Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)Mo-IV-nitrido complex generated by N-2 splitting is reported. The imido-hydride and di-hydride-amido Mo-IV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H)(2)(N(BPin)(2))](+) complex at room temperature results in the liberation of borylamines from the metal center.
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