Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 47, Pages 15553-15557Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201808578
Keywords
cycloaddition; heterocycles; photochemistry; radicals; reaction mechanisms
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Funding
- Beilstein-Institut
- DFG [HI628/13-1, RE3630]
- TU Dortmund
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Embedded medium-sized carbacycles and cyclohepta [b] indoles occur frequently as scaffold elements in natural products and bioactive compounds. Described herein is a conceptionally novel photochemically triggered cascade process to these scaffolds. Key to the cascading ring-expansion process is an unprecedented intramolecular alkyne analogue of the de Mayo reaction.
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