Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 37, Pages 12043-12047Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201807556
Keywords
electron transfer; layered compounds; magnetic properties; single-chain magnets; valence tautomerism
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [16H02269]
- Japan Society for the Promotion of Science [JP17H05137]
- E-IMR project
- Chinese Scholarship Council (CSC)
- Institute for Materials Research, Tohoku University
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A novel tetraoxolene-bridged Fe two-dimensional honeycomb layered compound, (NPr4)(2)[Fe-2(Cl(2)An)(3)]center dot 2(acetone)center dot H2O (1), where Cl(2)An(n-) = 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate and NPr4+ = tetrapropylammonium cation, has been synthesized. 1 revealed a thermally induced valence tautomeric transition at T-1/2 = 236K (cooling)/237K (heating) between Fem+ (m = 2 or 3) and Cl(2)An(n-) (n = 2 or 3) that induced valence modulations between [(FeHSFeHSIII)-Fe-II(Cl(2)An(2-))(2)(Cl(2)An(.3-))](2-) at T>T-1/2 and [(FeHSFeHSIII)-Fe-III(Cl(2)An(2-))(Cl(2)An(.3-))(2)](2-) at T
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