Journal
ORGANIC LETTERS
Volume 9, Issue 3, Pages 457-460Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062808f
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Funding
- NIGMS NIH HHS [GM071650, R01 GM071650-03, R01 GM071650] Funding Source: Medline
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The palladium-catalyzed carboamination of N-protected gamma-aminoalkenes with aryl bromides and triflates has been achieved under new, mild reaction conditions using the weak base Cs2CO3 in dioxane solvent. These reactions tolerate a wide variety of functional groups, including enolizable ketones, nitro groups, methyl esters, and acetates, which are not compatible with previously described conditions.
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