Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 10, Pages 3027-3031Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201806272
Keywords
benzo[b]phosphole; gold; mechanochromism; multistimuli-responsive materials; photochromism
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Funding
- UGC
- Strategically Oriented Research Theme (SORT) on Functional Materials for Molecular Electronics
- Research Grants Council (RGC) General Research Fund (GRF) of the Hong Kong Special Administrative Region, P. R. China [HKU 17305614]
- University Grants Committee (UGC) Areas of Excellence Scheme [AoE/P-03/08]
- University of Hong Kong
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A series of novel benzo[b]phosphole alkynylgold(I) complexes has been demonstrated to display photochromic and mechanochromic properties upon applying the respective stimuli of light and mechanical force. Promising multistimuli-responsive properties of this series of gold(I) complexes have been successfully achieved through judicious molecular design, which involves incorporation of the photochromic dithienylethene-containing benzo[b]phosphole into the triphenylamine-containing arylethynyl ligand that is susceptible to mechanical force-induced color changes via gold(I) complexation. With excellent thermal irreversibility and robust fatigue resistance of this series of gold(I) complexes, multicolor states controlled by the photochromism and mechanochromism have been realized. Repeatable photochromic and mechanochromic cycles without apparent loss of reactivity have also been observed under ambient conditions. The present work provides important insight and an alternative strategy for the molecular design of multistimuli-responsive materials, paving the way for further development of the underexplored photoresponsive gold(I) complexes and the multistate photocontrolled system.
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