Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 19, Pages 4910-4914Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402511
Keywords
alkyne; cross-coupling; fluorine; iron; synthetic methods
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Funding
- European Research Council (ERC) [257096]
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Iron catalysis has been developed for the intermolecular 1,2-addition of perfluoroalkyl iodides to alkynes and alkenes. The catalysis has a wide substrate scope and high functional-group tolerance. A variety of perfluoroalkyl iodides including CF3I can be employed. The resulting perfluoroalkylated alkyl and alkenyl iodides can be further functionalized by cross-coupling reactions. This methodology provides a straightforward and streamlined access to perfluoroalkylated organic molecules.
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