Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 25, Pages 6454-6458Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402950
Keywords
adsorption; conducting polymers; electrochemical synthesis; metal-organic frameworks; polyaniline
Categories
Funding
- National Natural Science Foundation of China [21390394]
- National Basic Research Program of China [2012CB821700, 2011CB808703]
- NSFC [21261130584, 91022030]
- 111 project [B07016]
- Award Project of KAUST [CRG-1-2012-LAI-009]
- Ministry of Education, Science and Technology Development Center Project [20120061130012]
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A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I-2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
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