Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 12, Pages 3635-3638Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201409247
Keywords
C-H activation; cobalt; cyanides; heterocycles; synthetic methods
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Funding
- European Research Council under the European Community [307535]
- Chinese Scholarship Program
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Carboxylate assistance proved to be the key for the success of efficient cobalt(III)-catalyzed C-H cyanations. Thus, an in situ generated cationic cobalt complex was identified as a versatile catalyst for the site-selective synthesis of various aromatic and heteroaromatic nitriles with ample substrate scope.
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