Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 6, Pages 1910-1913Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405252
Keywords
asymmetric catalysis; enantioselectivity; heterocycles; organocatalysis; synthetic methods
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Funding
- HKUST
- Hong Kong RGC [GRF604411, 604513, ECS605812, M-HKUST607/12]
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Described is an efficient catalytic asymmetric intermolecular CC bond-formation process to generate acyclic all-carbon quaternary stereocenters. The reactions overcome the unfavorable steric hindrance around reactive centers, and the competitive elimination (E1), to form a range of useful indole products with excellent efficiency and enantioselectivity.
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