Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 48, Pages 13042-13048Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406983
Keywords
electrocatalysis; homogeneous water oxidation; HO-OH coupling; nickel
Categories
Funding
- 973 Program of China [2012CB821706, 2014CB845602]
- NSFC [21331007, 21121061, 21203256]
- NSF of Guangdong Province [S2012030006240]
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The development of an earth-abundant, first-row water oxidation catalyst that operates at neutral pH and low overpotential remains a fundamental chemical challenge. Herein, we report the first nickel-based robust homogeneous water oxidation catalyst, which can electrocatalyze water oxidation at neutral pH and low overpotential in phosphate buffer. The results of DFT calculations verify that the O-O bond formation in catalytic water oxidation prefers a HO-OH coupling mechanism from a cis-isomer of the catalyst.
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