Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 33, Pages 8718-8721Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310865
Keywords
Bronsted acid catalysis; oxazolidinones; redox reactions; sulfoxides; ynamides
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Funding
- Max-Planck-Society
- University of Vienna
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A Bronsted acid catalyzed redox arylation of ynamides that employs aryl sulfoxides as the arylating agents is reported. This metal-free transformation proceeds at room temperature and efficiently affords alpha-arylated oxazolidinones in a redox-neutral, atom-economic fashion.
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