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Growth Actuated Bending and Twisting of Single Crystals

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 3, Pages 672-699

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201301223

Keywords

crystal growth; electron microscopy; helical structures; mechanical properties; X-ray diffraction

Funding

  1. US National Science Foundation [CHE-0845526, DMR-1105000]
  2. Provost's Office of New York University

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Crystals of a variety of substances including elements, minerals, simple salts, organic molecular crystals, and high polymers forgo long-range translational order by twisting and bending as they grow. These deviations have been observed in crystals ranging in size from nano-meters to centimeters. How and why so many materials choose dramatic non-crystallographic distortions is analyzed, with an emphasis on crystal chemistries that give rise to stresses operating either on surfaces of crystallites or within the bulk.

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