Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 15, Pages 3917-3921Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201400500
Keywords
allenes; carbenes; cross-coupling; furans; palladium
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Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- Natural Science Foundation of China [21332002, 21272010, 21172005]
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Allenyl ketones are employed as coupling partners in palladium-catalyzed oxidative cross-coupling reactions with organoboronic acids. This reaction constitutes an efficient methodology for the synthesis of highly substituted furan derivatives. Palladium-carbene migratory insertion is proposed as the key step in this transformation.
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