Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 48, Pages 13159-13163Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408371
Keywords
boron; carbine; carbon monoxide; dihydrogen activation; main-group adducts
Categories
Funding
- NSF [CHE-1359809]
- DOE [DE-FG02-13ER16370]
- NSERC of Canada
- Canada Research Chair
- University of Toronto
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1359809] Funding Source: National Science Foundation
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A one-electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)-bis(trimethylsilyl)aminodichloroborane adduct leads to a stable aminoboryl radical. A second one-electron reduction gives rise to a CAAC-aminoborylene adduct, which features an allenic structure. However, in manner similar to that of stable electrophilic singlet carbenes, this compound activates small molecules, such as CO and H-2.
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