Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 25, Pages 6538-6541Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403693
Keywords
carbene ligands; hydrodefluorination; hydrosilylation; Lewis acids; phosphonium salts
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Funding
- NSERC of Canada
- Canada Research Chair
- Alexander von Humboldt Foundation
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The dicationic imidazolium-phosphonium salt [(SIMes) PFPh2][B(C6F5)(4)](2) has been prepared and shown to exhibit remarkable Lewis acidity in stoichiometric reactions and acting as an effective Lewis acid catalyst for the hydrodefluorination of fluoroalkanes and the hydrosilylation of olefins.
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