Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 7, Pages 1799-1803Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308855
Keywords
boronate esters; cross-coupling; homogeneous catalysis; N-heterocyclic carbenes; Suzuki-Miyaura
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Funding
- Alexander von Humboldt Foundation (AvH)
- NSFC [21221062]
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A new catalytic system based on a Zn-II NHC precursor has been developed for the cross-coupling reaction of alkyl halides with diboron reagents, which represents a novel use of a GroupXII catalyst for CX borylation. This approach gives borylations of unactivated primary, secondary, and tertiary alkyl halides at room temperature to furnish alkyl boronates, with good functional-group compatibility, under mild conditions. Preliminary mechanistic investigations demonstrated that this borylation reaction seems to involve one-electron processes.
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