Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 7, Pages 2236-2240Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410523
Keywords
chirality; lanthanides; luminescence; molecular ferroelectrics; single-ion magnets
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Funding
- University Montpellier II
- CNRS
- EU/FEDER COMPETE [Pest-C/CTM/LA0011/2013, FCOMP-01-0124-FEDER-037271]
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Multifunctional molecular ferroelectrics are exciting materials synthesized using molecular chemistry concepts, which may combine a spontaneous electrical polarization, switched upon applying an electric field, with another physical property. A high-temperature ferroelectric material is presented that is based on a chiral Zn2+/Dy3+ complex exhibiting Dy3+ luminescence, optical activity, and magnetism. We investigate the correlations between the electric polarization and the crystal structure as well as between the low-temperature magnetic slow relaxation and the optical properties.
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