Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 43, Pages 11538-11542Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406811
Keywords
carbon nitride; enzyme catalysis; hydrogen production; hydrogenases; photocatalysis
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Funding
- Christian Doppler Research Association (Austrian Federal Ministry of Science, Research, and Economy)
- Christian Doppler Research Association (National Foundation for Research, Technology, and Development)
- OMV Group
- EPSRC [EP/H00338X/2]
- Marie Curie fellowship [GAN 624997]
- Max Planck Society
- Deutsche Forschungsgemeinschaft [LO 1801/1-1]
- Nanosystems Initiative Munich (NIM)
- Fonds der Chemischen Industrie (FCI)
- EPSRC [EP/H00338X/2, EP/H00338X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H00338X/2, EP/H00338X/1] Funding Source: researchfish
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Solar-light-driven H-2 production in water with a [NiFeSe]-hydrogenase (H(2)ase) and a bioinspired synthetic nickel catalyst (NiP) in combination with a heptazine carbon nitride polymer, melon (CNx), is reported. The semibiological and purely synthetic systems show catalytic activity during solar light irradiation with turnover numbers (TONs) of more than 50000molH(2)(molH(2)ase)(-1) and approximately 155molH(2)(molNiP)(-1) in redox-mediator-free aqueous solution at pH6 and 4.5, respectively. Both systems maintained a reduced photoactivity under UV-free solar light irradiation (>420 nm).
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