Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 1, Pages 149-154Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201409334
Keywords
carboxylate ligands; host-guest systems; mesoporous materials; metal-organic frameworks; zirconium
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Funding
- U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences
- Office of Naval Research [N000141310753]
- U.S. DOE [DE-AC02-06CH11357]
- Knut & Alice Wallenberg Foundation [3DEM-NATUR]
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Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.
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