Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 12, Pages 3173-3177Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310317
Keywords
carboranes; clusters; electrochemistry; magnesium; rechargeable batteries
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Funding
- Toyota Motor Engineering and Manufacturing North America Inc.
- NSF [CHE-0840456]
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Boron clusters are proposed as a new concept for the design of magnesium-battery electrolytes that are magnesium-battery-compatible, highly stable, and noncorrosive. A novel carborane-based electrolyte incorporating an unprecedented magnesium-centered complex anion is reported and shown to perform well as a magnesium-battery electrolyte. This finding opens a new approach towards the design of electrolytes whose likelihood of meeting the challenging design targets for magnesium-battery electrolytes is very high.
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