Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 13, Pages 3418-3421Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309248
Keywords
metal-support interactions; electronic structure; heterogeneous catalysis; oxygen activation; single-atom catalysis
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Funding
- NSFC [21277032]
- NCET [120131]
- SCAPC [201306]
- Netherlands-China exchange program [13CDP013]
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The synthesis of single-atom catalysts and the control of the electronic properties of catalytic sites to arrive at superior catalysts is a major challenge in heterogeneous catalysis. A stable supported single-atom silver catalyst with a controllable electronic state was obtained by anti-Ostwald ripening. An electronic perturbation of the catalytic sites that is induced by a subtle change in the structure of the support has a strong influence on the intrinsic reactivity. The higher depletion of the 4delectronic state of the silver atoms causes stronger electronic metal-support interactions, which leads to easier reducibility and higher catalytic activity. These results may improve our understanding of the nature of electronic metal-support interactions and lead to structure-activity correlations.
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