Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 24, Pages 6090-6094Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402192
Keywords
cycloaddition; noncovalent interactions; platinum; polymers; supramolecular chemistry
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Funding
- National Natural Science Foundation of China [21274139, 91227119]
- Fundamental Research Funds for the Central Universities [WK2060200012]
- Anhui Provincial Natural Science Foundation [1208085QB22]
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Supramolecular polymers are constructed based on the novel bis[alkynylplatinum(II)] terpyridine molecular tweezer/pyrene recognition motif. Successive addition of anthracene as the diene and cyano-functionalized dienophile triggers the reversible supramolecular polymerization process, thus advancing the concept of utilizing Diels-Alder chemistry to access stimuli-responsive materials in compartmentalized systems.
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