Journal
BIOMACROMOLECULES
Volume 8, Issue 2, Pages 327-330Publisher
AMER CHEMICAL SOC
DOI: 10.1021/bm061010g
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The optimized reaction conditions for the Cu(I)-catalyzed N -> C polymerization of azido-phenylalanyl-alanyl-propargyl amide to yield either high molecular weight linear polymers or medium-sized cyclic polymers is described. These reaction conditions will be applied to tailor the synthesis, properties, and structure of biologically relevant peptide-based biopolymers.
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