Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 48, Pages 13264-13268Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405478
Keywords
C-H functionalization; Heck reaction; photocatalysis; superoxide
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Funding
- European Research Council under the European Union/ERC [617044 (SunCatChem)]
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A combined palladium- and photoredox-catalyzed C-H olefination enables the synthesis of indoles. By using visible light, the direct C-H activation of aromatic enamines can be achieved and a variety of indole derivatives can be obtained in good yields under mild reaction conditions.
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