Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 24, Pages 6211-6215Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402924
Keywords
allylation; bimetallic catalysis; C-C coupling; gold catalysis; oxidative addition
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Funding
- NIHGMS [RO1 GM073932]
- NSF GRFP
- ARCS foundation
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A sp(3)-sp(2) C-C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino) amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C Br oxidative addition, and C-C reductive elimination in a model gold complex are shown. We expect that this method will serve as a platform for the development of novel transformations involving redox-active gold catalysts.
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