Related references
Note: Only part of the references are listed.Synthesis of gem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br
Lingchun Li et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Synthesis of Difluoromethyl Ethers with Difluoromethyltriflate
Patrick S. Fier et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base
Mingyou Hu et al.
JOURNAL OF FLUORINE CHEMISTRY (2013)
Use of Fluoroform as a Source of Difluorocarbene in the Synthesis of Difluoromethoxy- and Difluorothiomethoxyarenes
Charles S. Thomoson et al.
JOURNAL OF ORGANIC CHEMISTRY (2013)
Selective O-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents
Guokai Liu et al.
ORGANIC LETTERS (2013)
Copper-Catalyzed Difluoromethylation of ss,?-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation
Zhengbiao He et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Copper-Catalyzed Di- and Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations
Zhengbiao He et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Umpolung of Fluoroform by C?F Bond Activation: Direct Difluoromethylation of Lithium Enolates
Toshiaki Iida et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones
Xiao Shen et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds
Yanchuan Zhao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
A New Reagent for Direct Difluoromethylation
Yuta Fujiwara et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Efficient synthesis of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts for electrophilic bromodifluoromethylating reagents
Guokai Liu et al.
NEW JOURNAL OF CHEMISTRY (2012)
Efficient Difluoromethylation of sp3 Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases
Guokai Liu et al.
CHEMISTRYOPEN (2012)
Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters
Yu-Dong Yang et al.
CHEMISTRYOPEN (2012)
Inherent Oxygen Preference in Enolate Monofluoromethylation and a Synthetic Entry to Monofluoromethyl Ethers
Yoshinori Nomura et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation
G. K. Surya Prakash et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source
Fei Wang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes
Fei Wang et al.
CHEMICAL COMMUNICATIONS (2011)
N,N-Dimethyl-S-difluoromethyl-S-phenylsulfoximinium tetrafluoroborate: A versatile electrophilic difluoromethylating reagent
G. K. Surya Prakash et al.
JOURNAL OF FLUORINE CHEMISTRY (2011)
Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature
Yanchuan Zhao et al.
ORGANIC LETTERS (2011)
Efficient Access to Extended Yagupolskii-Umemoto-Type Reagents: Triflic Acid Catalyzed Intramolecular Cyclization of ortho-Ethynylaryltrifluoromethylsulfanes
Andrej Matsnev et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)
Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones
Yanchuan Zhao et al.
ORGANIC LETTERS (2010)
Selective difluoromethylation and monofluoromethylation reactions
Jinbo Hu et al.
CHEMICAL COMMUNICATIONS (2009)
Fluoride-Catalyzed Addition of PhSCF2SiMe3 to N-Substituted Cyclic Imides Followed by Radical Cyclization: General Synthetic Strategy of gem-Difluoromethylenated 1-Azabicyclic Compounds
Teerawut Bootwicha et al.
JOURNAL OF ORGANIC CHEMISTRY (2009)
N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles
Wei Zhang et al.
ORGANIC LETTERS (2009)
Fluorinated Johnson reagent for transfer-trifluoromethylation to carbon nucleophiles
Shun Noritake et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2008)
Fluorination in medicinal chemistry: Methods, strategies, and recent developments
Kenneth L. Kirk
ORGANIC PROCESS RESEARCH & DEVELOPMENT (2008)
Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)-CF2SO2Ph reagent
Wei Zhang et al.
TETRAHEDRON LETTERS (2008)
The preparation of HCF2CdX and HCF2ZnX via direct insertion into the carbon halogen bond of CF2HY (Y = Br, I)
Donald J. Burton et al.
JOURNAL OF FLUORINE CHEMISTRY (2007)
Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone
Ya Li et al.
JOURNAL OF ORGANIC CHEMISTRY (2007)
New electrophilic difluoromethylating reagent
G. K. Surya Prakash et al.
ORGANIC LETTERS (2007)
Chlorodifluoromethyl phenyl sulfone: a novel non-ozone-depleting substance-based difluorocarbene reagent for O- and N-difluoromethylations
Ji Zheng et al.
CHEMICAL COMMUNICATIONS (2007)
A remarkably efficient fluoroalkylation of cyclic sulfates and sulfamidates with PhSO2CF2H: Facile entry into beta-difluoromethylated or beta-difluoromethylenated alcohols and amines
Chuanfa Ni et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)
Stereoselective difluoromethylenation using Me3SiCF2SPh: Synthesis of chiral 2,4-disubstituted 3,3-difluoropyrrolidines
Ya Li et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)
2-chloro-2,2-difluoroacetophenone: A non-ODS-based difluorocarbene precursor and its use in the difluoromethylation of phenol derivatives
Laijun Zhang et al.
JOURNAL OF ORGANIC CHEMISTRY (2006)
Facile one-pot synthesis of N-difluoromethyl-2-pyridone derivatives
Makoto Ando et al.
ORGANIC LETTERS (2006)
Nucleophilic difluoromethylation of carbonyl compounds using TMSCF2SO2Ph and Mg0-mediated desulfonylation
CF Ni et al.
TETRAHEDRON LETTERS (2005)
Synthesis and transformation of [difluoro(phenylseleno)methyl]trimethylsilane
YY Qin et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone
GKS Prakash et al.
JOURNAL OF FLUORINE CHEMISTRY (2005)
Facile synthesis of chiral alpha-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines
Y Li et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
Difluoromethyl phenyl sulfone, a difluoromethylidene equivalent: Use in the synthesis of 1,1-difluoro-1-alkenes
GKS Prakash et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)
Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block
V Reutrakul et al.
JOURNAL OF ORGANIC CHEMISTRY (2004)
Stereoselective synthesis of anti-α-(difluoromethyl)-β-amino alcohols by boronic acid based three-component condensation.: Stereoselective preparation of (2S,3R)-difluorothreonine
GKS Prakash et al.
JOURNAL OF ORGANIC CHEMISTRY (2002)
A designed P1 cysteine mimetic for covalent and non-covalent inhibitors of HCVNS3 protease
F Narjes et al.
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS (2002)
A novel and highly efficient synthesis of gem-difluorocyclopropanes
F Tian et al.
ORGANIC LETTERS (2000)