Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 21, Pages 5444-5448Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403015
Keywords
carbenes; gold; heterocycles; nitrogen oxides; synthetic methods
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Funding
- National Science Council, Taiwan
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We report the first success in the gold-catalyzed oxoarylations of nitriles with pyridine-derived N-oxides using gold carbenes as initiators. These oxoarylations were also achieved satisfactorily in intermolecular three-component oxidations, including diverse alkenyldiazo esters, nitriles, and pyridine-based oxides.
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