Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 35, Pages 9380-9383Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403213
Keywords
arynes; azaborines; azides; reactive intermediates; thermolysis
Categories
Funding
- DFG
- Fonds der Chemischen Industrie
Ask authors/readers for more resources
Thermolysis of 9-azido-9-borafluorene in heptane solution produces the tetramer of a BN-phenanthryne. The isolation of the self-trapping product provides evidence for the involvement of the BN-aryne in the thermolysis reaction. Its formation may be rationalized by denitrogenation of the azide and ring enlargement.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available