Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 12, Pages 3227-3231Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310530
Keywords
alkynes; carbocycles; chirality; copper; cycloisomerization
Categories
Funding
- Aix-Marseille Universite
- CNRS
- ANR (JCJC MOCER2)
- Region Paca
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An original synthesis of chiral benzofulvenes triggered by organocopper reagents is reported. These enantiopure products are available through a highly chemo-, regio-, diastereo-, and enantioselective bis(alkylating) cycloisomerization process. A double chirality transfer (central-to-axial-to-central) is observed.
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