4.8 Review

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 4, Pages 1082-1096

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407701

Keywords

boron; cross-coupling; homogeneous catalysis; palladium; synthetic methods

Funding

  1. EPSRC [EP/K03927X/1, EP/I038071/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/K03927X/1, EP/I038071/1] Funding Source: researchfish

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This Minireview highlights advances in the Suzuki-Miyaura cross-coupling of secondary boron reagents for the creation of CC bonds with control of stereochemistry. It also includes non-transition-metal coupling of secondary and tertiary boronic esters to electron-rich aromatics.

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