Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 7, Pages 1881-1886Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309991
Keywords
alkenes; azides; copper; fluorine; synthetic methods
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Funding
- National Natural Science Foundation of China [21225210, 21121062, 20923005]
- National Basic Research Program of China [973-2011CB808700]
- Science Technology Commission of the Shanghai Municipality [11JC1415000]
- CAS/SAFEA International Partnership Program for Creative Research Teams
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A novel copper-catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF3-containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF3-containing amine derivatives.
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