Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 5, Pages 1651-1656Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410612
Keywords
crystal engineering; luminescence; metal-organic frameworks; microporous materials; sensors
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Funding
- National Science Foundation [DMR-1410169]
- La Ligue Contre le Cancer, La Region Centre
- Institut National de la Sante et de la Recherche Medicale
- MRSEC program of the National Science Foundation at the Materials Research Center of Northwestern University [DMR-1121262]
- Department of Chemistry of the University of Ioannina [2011/S 29-048013]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1410169] Funding Source: National Science Foundation
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The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
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