Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 19, Pages 4945-4949Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402562
Keywords
CH activation; dihydroquinolinones; palladacycles; palladium; synthetic methods
Categories
Funding
- NSFC [J1030413, 20925207, 20821062]
- 973 Project from the MOST of China [2009CB825300]
Ask authors/readers for more resources
3,4-Dihydroquinolinones were synthesized by the palladium-catalyzed, oxidative-addition-initiated activation and arylation of inert C(sp(3))H bonds. Pd(OAc)(2) and P(o-tol)(3) were used as the catalyst and ligand, respectively, to improve the efficiency of the reaction. A further advantage of this reaction is that it could be performed in air. A relatively rare seven-membered palladacycle was proposed as a key intermediate of the catalytic cycle.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available