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cis-Bis(2,2′-bipyridine)difluorochromium(III) perchlorate

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BLACKWELL PUBLISHING
DOI: 10.1107/S1600536807003157

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In the title compound, cis-[CrF2(C10H8N2)(2)]ClO4, the Cr-III ion is coordinated by the four N atoms [Cr-N = 2.0480 ( 14)2.0842 ( 14) angstrom] from two 2,2'-bipyridine ligands and two F- ions [Cr-F = 1.8409 ( 10) and 1.8541 ( 10) A] in a distorted octahedral arrangement. The crystal packing is stabilized by pi-pi interactions and weak intermolecular C - H center dot center dot center dot F and C-H H center dot center dot center dot O hydrogen bonds.

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