Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 34, Pages 9007-9011Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404173
Keywords
allenes; allylic compounds; boron; C-C coupling; copper
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Funding
- MEXT (Japan)
- JSPS for Young Scientists
- Grants-in-Aid for Scientific Research [25105731] Funding Source: KAKEN
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Borylative allyl-allyl coupling using allenes, bis(pinacolato) diboron, and allyl phosphates has been developed in the presence of a copper catalyst bearing an N-heterocyclic carbene ligand. The reaction affords boryl-substituted 1,5-diene derivatives in good to high yields with high regioselectivity and Z selectivity.
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