Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 47, Pages 12771-12775Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406761
Keywords
cluster compounds; gold; luminescence; metal-organic frameworks; solvatochromism
Categories
Funding
- 973 program [2014CB845603]
- National Natural Science Foundation of China [21125102, 21390390]
Ask authors/readers for more resources
A cluster-based luminescent porous metal-organic framework has been constructed through a cluster linker approach. The luminescent gold(I) cluster, prefunctionalized with pyrazinyl groups, was used as a cluster linker, similar to an organic linker, to connect silver ions in order to form a 3D framework. 1D channels with 1.1 nm diameter were observed in the framework. The cluster with its intrinsic luminescence was incorporated into a porous framework to give a luminescent bifunctional NbO net. This MOF shows solvatochromic behavior, and the interactions between solvent molecules and silver ions inside the channels account for the changes in absorption and emission spectra.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available