Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 3, Pages 823-830Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061800g
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tert-Butyl hydroperoxide catalyzed by (5,10,15,20-tetramesitylporphyrinate) osmium(II) carbonyl [Os(TMP)CO] complex was found to be a highly efficient versatile oxidant for C-H carbons in steroid substrates. When reacted with representative steroids with an estrane, pregnane, 5 beta-cholane, or 5 alpha-cholestane structure, regioselective oxyfunctionalization and/or oxidative degradation occurred to give a variety of novel and uncommon derivatives in one step.
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