Journal
PHYSICAL REVIEW LETTERS
Volume 98, Issue 5, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.98.057401
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Structural changes of the iron(II)-tris-bipyridine ([Fen(II)(bpy)(3)](2+)) complex induced by ultrashort pulse excitation and population of its short-lived (<= 0.6 ns) quintet high spin state have been detected by picosecond x-ray absorption spectroscopy. The structural relaxation from the high spin to the low spin state was followed over the entire lifetime of the excited state. A combined analysis of the x-ray absorption near-edge structure and extended x-ray-absorption fine structure spectroscopy features delivers an Fe-N bond elongation of 0.2 angstrom in the quintet state compared to the singlet ground state.
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