Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 208, Issue 3, Pages 277-286Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200600492
Keywords
photodecomposition; polycondensation; spin coating; structure-property relations; thin films
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An improved synthesis of photosensitive homopolymers containing aryltriazene chromophores covalently incorporated into the polymer backbone is reported. Such photopolymers proved to have promising properties for novel UV-laser applications. A homologous series of new aryltriazene polymers with increasingly branched side chains (R=Me, Et, iPr, tBu) was synthesized and characterized. Homogeneous thin films with thicknesses from approximate to 15 to > 150 nm were prepared by spin-coating. Photodecomposition was studied in solution and on thin films. Polymers with increasingly branched and bulky substituents showed decreasing photodissociation rates. NMR studies suggested an enhanced hindrance of the N(2)-N(3) bond rotation in the aryltriazene moiety with increasing steric demand of the substituents.
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