4.4 Article

Direct oxidative conversion of aldehydes and alcohols to 2-imidazolines and 2-oxazolines using molecular iodine

Journal

TETRAHEDRON
Volume 63, Issue 6, Pages 1474-1480

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.11.077

Keywords

2-imidazoline; 2-oxazoline; iodine; alcohol; aldehyde; ethylenediamine; aminoethanol

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Aldehydes were converted to the corresponding 2-imidazolines and 2-oxazolines in good yields by the reaction with ethylenediamine and aminoethanol, respectively, using molecular iodine and potassium carbonate. Moreover, primary alcohols were directly converted to the corresponding 2-imidazolines and 2-oxazolines via aldehydes in one-pot manner with ethylenediamine and aminoethanol, respectively, using molecular iodine and potassium carbonate. (c) 2006 Published by Elsevier Ltd.

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