Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 6, Pages 1626-1629Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309764
Keywords
cerium; crystal structure; density functional calculations; multiple bonds
Categories
Funding
- Hong Kong Research Grants Council [602310]
- Hong Kong University of Science and Technology
Ask authors/readers for more resources
Whereas terminal oxo complexes of transition and actinide elements are well documented, analogous lanthanide complexes have not been reported to date. Herein, we report the synthesis and structure of a cerium(IV) oxo complex, [CeO(L-OEt)(2)(H2O)]MeC(O)NH2 (1; L-OEt(-)=[Co((5)-C5H5){P(O)(OEt)(2)}(3)](-)), featuring a short CeO bond (1.857(3)angstrom). DFT calculations indicate that the hydrogen bond to cocrystallized acetamide plays a key role in stabilizing the CeO moiety of 1 in the solid state. Complex 1 exhibits oxidizing and nucleophilic reactivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
